Resumen
Teniendo en cuenta el potencial de los cementos geopoliméricos como una alternativa para sustituir parcialmente al cemento Portland, este artículo presenta el análisis del efecto que tienen las condiciones de curado de los cementos geopoliméricos sobre su desempeño mecánico. Las variables evaluadas durante el proceso de curado fueron tiempo, humedad y temperatura. Además, se describe el comportamiento de estas variables de acuerdo con los métodos de curado que han sido estudiados y evaluados hasta el momento en los cementos geopoliméricos con base de ceniza volante. Para llevar a cabo la revisión bibliográfica fue usado Scopus como herramienta principal de búsqueda, a partir de la palabra clave “cementos geopoliméricos”. Se identificaron más de 90 documentos relevantes tras aplicar filtros específicos y revisar sus resúmenes. Finalmente, se realizó una lectura y análisis detallado de los datos bibliográficos, que aportaron información relevante para el tema de estudio. Los procedimientos publicados muestran que no hay unanimidad para definir el mejor método de curado para este tipo de material; sin embargo, las condiciones más aceptadas para el desarrollo de mayores resistencias a la compresión son temperaturas entre 60 y 80 °C, con humedad controlada (sellado), durante un periodo de 4 a 12 horas. En general, esta revisión sirve como una guía para proponer, estudiar y aplicar diferentes procesos de curado en cementos geopoliméricos con base de ceniza volante, buscando optimizar su desempeño mecánico.
Citas
Adjei, Stephen; Elkatatny, Salaheldin; Aggrey, Wilberforce; Abdelraouf, Yasmin (2022). Geopolymer as the future oil-well cement: A review. Journal of Petroleum Science and Engineering, 208, 109485. https://doi.org/https://doi.org/10.1016/j.petrol.2021.109485
Al Bakri, Mohd; Kamarudin, Hussin; BinHussain, Mohammed; Khairul, Ismail; Zarina, Yahya; Rafiza, Abdul (2011). The Effect of Curing Temperature on Physical and Chemical Properties of Geopolymers. Physics Procedia, 22, 286-291. https://doi.org/10.1016/j.phpro.2011.11.045
Aranda, Alfonso; López-Sabirón, Ana; Ferreira, Germán; Llera, Eva (2013). Uses of alternative fuels and raw materials in the cement industry as sustainable waste management options. Renewable and Sustainable Energy Reviews, 23, 242-260. https://doi.org/10.1016/j.rser.2013.02.024
Asghar, Raheel; Khan, Mohsin; Alyousef, Rayed; Javed, Muhammad; Ali, Mujahid (2023). Promoting the green Construction: Scientometric review on the mechanical and structural performance of geopolymer concrete. Construction and Building Materials, 368, 130502. https://doi.org/10.1016/J.CONBUILDMAT.2023.130502
Bahraq, Ashraf; Al-Osta, Mohammed; Al-Amoudi, Omar; Saleh, Tawfik; Obot, Ime (2022). Atomistic simulation of polymer-cement interactions: Progress and research challenges. Construction and Building Materials, 327, 126881. https://doi.org/10.1016/j.conbuildmat.2022.126881
Bakharev, Tatiana (2005). Geopolymeric materials prepared using Class F fly ash and elevated temperature curing. Cement and Concrete Research, 35(6), 1224-1232. https://doi.org/10.1016/j.cemconres.2004.06.031
Caballero, Erich; Sánchez, Wilson (2010). Síntesis de nuevos cementos geopoliméricos a partir de subproductos del proceso de extracción de oro en la mina La Baja, distrito de California, Santander [Tesis de pregrado]. Universidad Industrial de Santander.
Chen, Gai; Zheng, Dong-ping; Chen, Yi-wu; Lin, Jia-xiang; Lao, Wei-jian, Guo, Yong-chang; Chen, Zhan-biao; Lan, Xue-wei. (2023). Development of high performance geopolymer concrete with waste rubber and recycle steel fiber: A study on compressive behavior, carbon emissions and economical performance. Construction and Building Materials, 393, 131988. https://doi.org/10.1016/J.CONBUILDMAT.2023.131988
Chindaprasirt, Prinya; Jenjirapanya, Supichart; Rattanasak, Ubolluk (2014). Characterizations of FBC/PCC fly ash geopolymeric composites. Construction and Building Materials, 66(2), 72-78. https://doi.org/10.1016/j.conbuildmat.2014.05.067
Criado, María; Fernández-Jiménez, Ana; Palomo, Ángel (2007). Alkali activation of fly ash: Effect of the SiO2/Na2O ratio: Part I: FTIR study. Microporous and Mesoporous Materials, 106(1), 180-191. https://doi.org/10.1016/j.micromeso.2007.02.055
Criado, María; Fernández-Jiménez, Ana; Palomo, Ángel (2010). Alkali activation of fly ash. Part III: Effect of curing conditions on reaction and its graphical description. Fuel, 89(11), 3185-3192. https://doi.org/10.1016/j.fuel.2010.03.051
Criado, María; Fernández-Jiménez, Ana; Palomo, Ángel; Sobrados, Isabel; Sanz, Jesuìs (2008). Effect of the SiO2/Na2O ratio on the alkali activation of fly ash. Part II: 29Si MAS-NMR Survey. Microporous and Mesoporous Materials, 109(1), 525-534. https://doi.org/10.1016/j.micromeso.2007.05.062
Criado, María; Palomo, Ángel; Fernández-Jiménez, Ana (2005). Alkali activation of fly ashes. Part 1: Effect of curing conditions on the carbonation of the reaction products. Fuel, 84(16), 2048-2054. https://doi.org/10.1016/j.fuel.2005.03.030
Damineli, Bruno; Kemeid, Fernanda; Aguiar, Patricia; John, Vanderley (2010). Measuring the eco-efficiency of cement use. Cement and Concrete Composites, 32(8), 555-562. https://doi.org/10.1016/j.cemconcomp.2010.07.009
Damtoft, Jesper; Lukasik, Jacques; Herfort, Duncan; Sorrentino, Danielle; Gartner, Ellis (2008). Sustainable development and climate change initiatives. Cement and Concrete Research, 38(2), 115-127. https://doi.org/10.1016/j.cemconres.2007.09.008
Davidovits, Nicolas; Davidovics, Michel; Davidovits, Joseph (1989). Ceramic-ceramic composite material and production method (Patente EE. UU. Pat 4 888 3111989). Oficina de Patentes y Marcas Registradas.
Diaz-Loya, Ivan; Allouche, Erez; Vaidya, Saiprasad (2011). Mechanical properties of fly-ash-based geopolymer concrete. ACI Materials Journal, 108(3), 300-306. https://doi.org/620.1u40492–dc22
Echeverri-Aguirre, Mauled; Molina, Jarol; Hoyos-Montilla, Ary; Carvajal, Henry; Rudas, Sebastián (2022). Heat flow modelling of the alkaline activation of fly ash with sodium hydroxide in the presence of portlandite. Construction and Building Materials, 357, 129248. https://doi.org/10.1016/j.conbuildmat.2022.129248
Ettahiri, Youssef; Bouargane, Brahim; Fritah, Kamal; Akhsassi, Brahim; Pérez-Villarejo, Luis; Aziz, Ayoub; Bouna, Lahcen; Benlhachemi, Abdeljalil; Novais, Rui (2023). A state-of-the-art review of recent advances in porous geopolymer: Applications in adsorption of inorganic and organic contaminants in water. Construction and Building Materials, 395, 132269. https://doi.org/10.1016/j.conbuildmat.2023.132269
Fernández-Jiménez, Ana; Palomo, Ángel (2005). Composition and microstructure of alkali activated fly ash binder: Effect of the activator. Cement and Concrete Research, 35(10), 1984-1992. https://doi.org/10.1016/j.cemconres.2005.03.003
Fernández-Jiménez, Ana; Palomo, Ángel (2009). 6-Nanostructure/microstructure of fly ash geopolymers. En Provis, John; van Deventer, Jannie (Eds.), Geopolymers (pp. 89-117). Woodhead Publishing. https://doi.org/10.1533/9781845696382.1.89
Fernández-Jiménez, Ana; Palomo, Ángel; Criado, María (2005). Microstructure development of alkali activated fly ash cement: a descriptive model. Cement and Concrete Research, 35(6), 1204-1209. https://doi.org/10.1016/j.cemconres.2004.08.021
Fernández-Jiménez, Ana; Palomo, Ángel; Criado, María (2006). Alkali activated fly ash binders. A comparative study between sodium and potassium activators. Materiales de Construcción, 56(281), 51-65. https://doi.org/10.3989/mc.2006.v56.i281.92
Fernández-Jiménez, Ana; Palomo, Ángel; Pastor, José; Martín, Antonia (2008). New Cementitious Materials Based on Alkali‐Activated Fly Ash: Performance at High Temperatures. Journal of the American Ceramic Society, 91(10), 3308-3314. https://doi.org/10.1111/j.1551-2916.2008.02625.x
Fernández-Jiménez, Ana; Palomo, Ángel; Sobrados, Isabel; Sanz, Jesuìs (2006). The role played by the reactive alumina content in the alkaline activation of fly ashes. Microporous and Mesoporous Materials, 91(1), 111-119. https://doi.org/10.1016/j.micromeso.2005.11.015
Fletcher, Ross; MacKenzie, Kenneth; Nicholson, Catherine; Shimada, Shiro (2005). The composition range of aluminosilicate geopolymers. Journal of the European Ceramic Society, 25(9), 1471-1477. https://doi.org/10.1016/j.jeurceramsoc.2004.06.001
García-Lodeiro, Inés; Palomo, Ángel; Fernández-Jiménez, Ana (2015). 3-Crucial insights on the mix design of alkali-activated cement-based binders. En Pacheco, Fernando; Labrincha, João; Chindaprasirt, Prinya (Eds.), Handbook of Alkali-Activated Cements, Mortars and Concretes (pp. 49-73). Woodhead Publishing. https://doi.org/10.1533/9781782422884.1.49
García-Lodeiro, Inés; Palomo, Ángel; Fernández-Jiménez, Ana; Macphee, Donald (2011). Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O–CaO–Al2O3–SiO2–H2O. Cement and Concrete Research, 41(9), 923-931. https://doi.org/10.1016/j.cemconres.2011.05.006
Giasuddin, Haider; Sanjayan, Jay; Ranjith, Pathegama (2013). Strength of geopolymer cured in saline water in ambient conditions. Fuel, 107, 34-39. https://doi.org/10.1016/j.fuel.2013.01.035
Görhan, Gökhan; Aslaner, Ridvan; Şinik, Osman (2016). The effect of curing on the properties of metakaolin and fly ash-based geopolymer paste. Composites Part B: Engineering, 97, 329-335. https://doi.org/10.1016/j.compositesb.2016.05.019
Görhan, Gökhan; Kürklü, Gökhan (2014). The influence of the NaOH solution on the properties of the fly ash-based geopolymer mortar cured at different temperatures. Composites Part B: Engineering, 58, 371-377. https://doi.org/10.1016/j.compositesb.2013.10.082
Guo, Xiaolu; Shi, Huisheng; Dick, Warren (2010). Compressive strength and microstructural characteristics of class C fly ash geopolymer. Cement and Concrete Composites, 32(2), 142-147. https://doi.org/10.1016/j.cemconcomp.2009.11.003
Hasanbeigi, Ali; Price, Lynn; Lin, Elina (2012). Emerging energy-efficiency and CO2 emission-reduction technologies for cement and concrete production: A technical review. Renewable and Sustainable Energy Reviews, 16(8), 6220-6238. https://doi.org/10.1016/J.RSER.2012.07.019
Hossain, Md. Maruf; Karim, Md. Rezaul; Hossain, Mustaque; Islam, Md. Nazrul; Zain, Muhammad (2015). Durability of mortar and concrete containing alkali-activated binder with pozzolans: A review. Construction and Building Materials, 93, 95-109. https://doi.org/10.1016/j.conbuildmat.2015.05.094
Hoyos-Montilla, Ary; Arias-Jaramillo, Yhan; Tobón, Jorge (2018). Evaluation of cements obtained by alkali-activated coal ash with NaOH cured at low temperatures. Materiales de Construcción, 68(332), e170. https://doi.org/10.3989/mc.2018.10117
Hoyos-Montilla, Ary; Puertas, Francisca; Tobón, Jorge (2018a). Microcalorimetric study of the effect of calcium hydroxide and temperature on the alkaline activation of coal fly ash. Journal of Thermal Analysis and Calorimetry, 131(3), 2395-2410. https://doi.org/10.1007/s10973-017-6715-4
Hoyos-Montilla, Ary; Puertas, Francisca; Tobón, Jorge (2018b). Microcalorimetric study of the effect of calcium hydroxide and temperature on the alkaline activation of coal fly ash. Journal of Thermal Analysis and Calorimetry, 131(3), 2395-2410. https://doi.org/10.1007/s10973-017-6715-4
Hoyos-Montilla, Ary; Puertas, Francisca; Tobón, Jorge (2021). Study of the reaction stages of alkali-activated cementitious materials using microcalorimetry. Advances in Cement Research, 33(1), 1-13. https://doi.org/10.1680/jadcr.19.00025
İlkentapar, Serhan; Atiş, Cengiz; Karahan, Okan; Görür, Ela (2017). Influence of duration of heat curing and extra rest period after heat curing on the strength and transport characteristic of alkali activated class F fly ash geopolymer mortar. Construction and Building Materials, 151, 363-369. https://doi.org/10.1016/j.conbuildmat.2017.06.041
Johari, Megat; Brooks, Jeffrey; Kabir, Shahid; Rivard, Patrice (2011). Influence of supplementary cementitious materials on engineering properties of high strength concrete. Construction and Building Materials, 25(5), 2639-2648. https://doi.org/10.1016/j.conbuildmat.2010.12.013
Juenger, Maria; Siddique, Rafat (2015). Recent advances in understanding the role of supplementary cementitious materials in concrete. Cement and Concrete Research, 78(Parte A), 71-80. https://doi.org/10.1016/j.cemconres.2015.03.018
Kani, Ebrahim; Allahverdi, Ali (2009). Effects of curing time and temperature on strength development of inorganic polymeric binder based on natural pozzolan. Journal of Materials Science, 44, 3088-3097.
Khalil, Muhammad; Merz, Erich (1994). Immobilization of intermediate-level wastes in geopolymers. Journal of Nuclear Materials, 211(2), 141-148. https://doi.org/10.1016/0022-3115(94)90364-6
Kovalchuk, Georgiy; Fernández-Jiménez, Ana; Palomo, Ángel (2007). Alkali-activated fly ash: Effect of thermal curing conditions on mechanical and microstructural development - Part II. Fuel, 86(3), 315-322. https://doi.org/10.1016/j.fuel.2006.07.010
Kovalchuk, Georgiy; Palomo, Ángel; Fernández-Jiménez, Ana (2008). 1-Alkali-activated fly ash. Relationship between mechanical strength gains and initial ash chemistry. Materiales de Construcción, 58(291), 35-52. https://doi.org/10.3989/mc.2008.v58.i291.101
Krivenko, Pavel; Kovalchuk, Georgiy; Palomo, Ángel; Fernández-Jiménez, Ana (2006). Fly Ash Based Geocements: Genesis of Microstructure and Properties at Hydration-Dehydration Process. En Brandt, Andrzej (Ed.), Brittle Matrix Composites 8 (pp. 55-64). Woodhead Publishing. https://doi.org/10.1533/9780857093080.55
Liu, Jinliang; Shi, Xiaohui; Zhang, Guanhua; Li, Linfei (2023). Study the Mechanical Properties of Geopolymer under Different Curing Conditions. Minerals, 13(5), 690. https://doi.org/10.3390/min13050690
Lothenbach, Barbara; Scrivener, Karen; Hooton, Douglas (2011). Supplementary cementitious materials. Cement and Concrete Research, 41(12), 1244-1256. https://doi.org/10.1016/j.cemconres.2010.12.001
Nagral, Mohammed; Ostwal, Tejas; Chitawadaji, Manojkumar (2014). Effect of temperature and curing hours on the properties of geo-polymer concrete. International Journal of Computational Engineering Research, 4(9), 2250-3005.
Nath, Susanta; Maitra, Saikat; Mukherjee, Siddhartha; Kumar, Sanjay (2016). Microstructural and morphological evolution of fly ash based geopolymers. Construction and Building Materials, 111, 758-765. https://doi.org/10.1016/j.conbuildmat.2016.02.106
Nath, Susanta; Mukherjee, Siddhartha; Maitra, Saikat; Kumar, Sanjay (2017). Kinetics study of geopolymerization of fly ash using isothermal conduction calorimetry. Journal of Thermal Analysis and Calorimetry, 127(3), 1953-1961. https://doi.org/10.1007/s10973-016-5823-x
Nodehi, Mehrab; Taghvaee, Vahid (2021). Alkali-Activated Materials and Geopolymer: A Review of Common Precursors and Activators Addressing Circular Economy. Circular Economy and Sustainability, 2(1), 165-196. https://doi.org/10.1007/S43615-021-00029-W
Noushini, Amin; Castel, Arnaud (2016). The effect of heat-curing on transport properties of low-calcium fly ash-based geopolymer concrete. Construction and Building Materials, 112, 464-477. https://doi.org/10.1016/j.conbuildmat.2016.02.210
Okoye, Francis; Durgaprasad, Janjanam; Singh, Nakshatra (2015a). Fly ash/Kaolin based geopolymer green concretes and their mechanical properties. Data in Brief, 5, 739-744. https://doi.org/10.1016/j.dib.2015.10.029
Okoye, Francis; Durgaprasad, Janjanam; Singh, Nakshatra (2015b). Mechanical properties of alkali activated flyash/Kaolin based geopolymer concrete. Construction and Building Materials, 98, 685-691. https://doi.org/10.1016/j.conbuildmat.2015.08.009
Palomo, Ángel; Grutzeck, Michael; Blanco-Varela, Maríateresa (1999). Alkali-activated fly ashes: A cement for the future. Cement and Concrete Research, 29(8), 1323-1329. https://doi.org/10.1016/S0008-8846(98)00243-9
Parthasarathy, Pavithra; Srinivasula, Maddula; Dinakar, Pasala; Hanumantha, Bendadi; Satpathy, Bijaylaxmi; Mohanty, A. (2016). A mix design procedure for geopolymer concrete with fly ash. Journal of Cleaner Production, 133, 117-125. https://doi.org/10.1016/j.jclepro.2016.05.041
Phair, John; van Deventer, Jannie (2002). Characterization of fly-ash-based geopolymeric binders activated with sodium aluminate. Industrial & Engineering Chemistry Research, 41(17), 4242-4251.
Provis, John (2009). 4-Activating solution chemistry for geopolymers. En Provis, John; van Deventer, Jannie (Eds.), Geopolymers (pp. 50-71). Woodhead Publishing. https://doi.org/10.1533/9781845696382.1.50
Provis, John; Palomo, Ángel, Shi, Caijun (2015). Advances in understanding alkali-activated materials. Cement and Concrete Research, 78 (Parte A), 110-125. https://doi.org/10.1016/j.cemconres.2015.04.013
Puertas, Francisca; Fernández-Jiménez, Ana (2003). Mineralogical and microstructural characterisation of alkali-activated fly ash/slag pastes. Cement and Concrete Composites, 25(3), 287-292. https://doi.org/10.1016/S0958-9465(02)00059-8
Qureshi, Mohd. Nadeem; Ghosh, Sommath (2013). Alkali-activated blast furnace slag as a green construction material. IOSR, Journal of Mechanical and Civil Engineering, 2014, 24-28.
Rashad, Alaa (2014). A comprehensive overview about the influence of different admixtures and additives on the properties of alkali-activated fly ash. Materials & Design, 53, 1005-1025. https://doi.org/10.1016/j.matdes.2013.07.074
Riahi, Shadi; Nazari, Ali; Zaarei, Davood; Khalaj, Gholamreza; Bohlooli, Hamid; Kaykha, Mohammad (2012). Compressive strength of ash-based geopolymers at early ages designed by Taguchi method. Materials & Design, 37, 443-449. https://doi.org/10.1016/j.matdes.2012.01.030
Ruiz-Santaquiteria, Cristina; Fernández-Jiménez, Ana; Palomo, Ángel (2016). Alternative prime materials for developing new cements: Alkaline activation of alkali aluminosilicate glasses. Ceramics International, 42(8), 9333-9340. https://doi.org/10.1016/j.ceramint.2016.03.111
Ruiz-Santaquiteria, Cristina; Skibsted, Jørgen; Fernández-Jiménez, Ana; Palomo, Ángel (2012). Alkaline solution/binder ratio as a determining factor in the alkaline activation of aluminosilicates. Cement and Concrete Research, 42(9), 1242-1251. https://doi.org/10.1016/j.cemconres.2012.05.019
Ryu, Gum; Lee, Young; Koh, Kyung; Chung, Young (2013). The mechanical properties of fly ash-based geopolymer concrete with alkaline activators. Construction and Building Materials, 47, 409-418. https://doi.org/10.1016/j.conbuildmat.2013.05.069
Sajan, Pudasaini; Jiang, Tengyao; Lau, ChooiKim; Tan, Gang; Ng, Kam (2021). Combined effect of curing temperature, curing period and alkaline concentration on the mechanical properties of fly ash-based geopolymer. Cleaner Materials, 1, 100002. https://doi.org/10.1016/j.clema.2021.100002
Salih, Moslih; Farzadnia, Nima; Abang-Ali, Abang-Abdullah; Demirboga, Ramazan (2015). Effect of different curing temperatures on alkali activated palm oil fuel ash paste. Construction and Building Materials, 94, 116-125. https://doi.org/10.1016/j.conbuildmat.2015.06.052
Satpute-Manesh, B.; Wakchaure-Madhukar, R.; Patankar Subhash, V. (2012). Effect of Duration and Temperature of Curing on Compressive Strength of Geopolymer Concrete. International Journal of Engineering and Innovative Technology, 1(5), 152-155.
Shi, Caijun; Fernández-Jiménez, Ana; Palomo, Ángel (2011). New cements for the 21st century: The pursuit of an alternative to Portland cement. Cement and Concrete Research, 41(7), 750-763. https://doi.org/10.1016/j.cemconres.2011.03.016
Singh, Brajeshwar; Rahman, Md. Reyazur; Paswan, Rakesh; Bhattacharyya, Sriman (2016). Effect of activator concentration on the strength, ITZ and drying shrinkage of fly ash/slag geopolymer concrete. Construction and Building Materials, 118, 171-179. https://doi.org/10.1016/j.conbuildmat.2016.05.008
Steveson, Michael; Sagoe-Crentsil, Kwesi (2005). Relationships between composition, structure, and strength of inorganic polymers. Part 2. Fly ash-derived inorganic polymers. Journal of Materials Science, 40, 4247-4259.
Swanepoel, J. C.; Strydom, Christien (2002). Utilisation of fly ash in a geopolymeric material. Applied Geochemistry, 17(8), 1143-1148. https://doi.org/10.1016/S0883-2927(02)00005-7
Van Jaarsveld, J.; van Deventer, Jannie; Lukey, Grant (2002). The effect of composition and temperature on the properties of fly ash- and kaolinite-based geopolymers. Chemical Engineering Journal, 89(1), 63-73. https://doi.org/10.1016/S1385-8947(02)00025-6
Villar-Cociña, Ernesto; Morales, Eduardo; Santos, Sergio; Savastano, Holmer; Frías, Moisés (2011). Pozzolanic behavior of bamboo leaf ash: Characterization and determination of the kinetic parameters. Cement and Concrete Composites, 33(1), 68-73. https://doi.org/10.1016/j.cemconcomp.2010.09.003
Wardhono, Arie; Law, David; Strano, Anthony (2015). The Strength of Alkali-activated Slag/fly Ash Mortar Blends at Ambient Temperature. Procedia Engineering, 125, 650-656. https://doi.org/10.1016/j.proeng.2015.11.095
Williamson, Trevor; Juenger, Maria (2016). The role of activating solution concentration on alkali–silica reaction in alkali-activated fly ash concrete. Cement and Concrete Research, 83, 124-130. https://doi.org/10.1016/j.cemconres.2016.02.008
Xie, Tianyu; Ozbakkaloglu, Togay (2015). Behavior of low-calcium fly and bottom ash-based geopolymer concrete cured at ambient temperature. Ceramics International, 41(4), 5945-5958. https://doi.org/10.1016/j.ceramint.2015.01.031
Zhang, Zuhua; Li, Liangfeng; Ma, Xue; Wang, Hao (2016). Compositional, microstructural and mechanical properties of ambient condition cured alkali-activated cement. Construction and Building Materials, 113, 237-245. https://doi.org/10.1016/j.conbuildmat.2016.03.043
Zhang, Zuhua; Wang, Hao; Zhu, Yingcan; Reid, Andrew; Provis, John; Bullen, Frank (2014). Using fly ash to partially substitute metakaolin in geopolymer synthesis. Applied Clay Science, 88-89, 194-201. https://doi.org/10.1016/j.clay.2013.12.025
Zhou, Wei; Yan, Chunjie; Duan, Ping; Liu, Yi; Zhang, Zuhua; Qiu, Xiumei; Li, Dan (2016). A comparative study of high- and low-Al2O3 fly ash based-geopolymers: The role of mix proportion factors and curing temperature. Materials & Design, 95, 63-74. https://doi.org/10.1016/j.matdes.2016.01.084
Zhuang, Xiao-Yu; Chen, Liang; Komarneni, Sridhar; Zhou, Chun-Hui; Tong, Dong-Shen; Yang, Hui-Min; Yu, Wei-Hua; Wang, Hao (2016). Fly ash-based geopolymer: clean production, properties and applications. Journal of Cleaner Production, 125, 253-267. https://doi.org/10.1016/j.jclepro.2016.03.019

Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.
Derechos de autor 2024 Servicio Nacional de Aprendizaje SENA















