Abstract
The effect of exposing metakaolin-based geopolymers to a temperature of 1200 °C was assessed using as alkaline activator a mixture of potassium hydroxide with different sources of silica: a commercial potassium silicate (PS), rice husk ash (RHA), and silica fume (SF). The amounts of metakaolin and activator in the mixture were adjusted to obtain molar ratios of 2.5 for SiO2/Al2O3 and 0,28 for K2O/SiO2. The substitution of 50% PS with RHA and SF was also studied, and the resistance to compression after exposing the mixture to different temperatures between 300 and 1200 °C was assessed. The respective physical analyses, such as determination of volumetric changes, were performed, and the study was complemented with a microstructural analysis conducted by X-ray diffraction and electron microscopy. At room temperature, the geopolymers presented mechanical strengths ranging between ~30 and ~36 MPa. At 1200 °C, materials originally amorphous were transformed into crystalline-type structures, specifically leucite and kalsilite. The best thermo-mechanical performance of the geopolymers was achieved by replacing 50% PS with CCA, which when exposed to 1200 °C retains 44% of its mechanical strength as compared with 26% retained by the reference material.
References
Bell, J. L.; Driemeyer, P.E.; and Kriven, W. M. (2009).
Formation of Ceramics from Metakaolin-Based Geopolymers:
Part I-Cs-Based Geopolymer. Journal of the American Ceramic
Society, 92, 1–8. DOI:10.1111/j.1551-2916.2008.02790.x
https://doi.org/10.1111/j.1551-2916.2008.02790.x
Ben Haha, M.; Le Saout, G.; Winnefeld, F.; and Lothenbach,
B. (2011). Influence of activator type on hydration kinetics,
hydrate assemblage and microstructural development of
alkali activated blast-furnace slags. Cement and Concrete
Research, 41, 301–310.
Bernal, S.A.; Rodriguez, E.D.; Mejía de Gutierrez , R.;
Gordillo, M.; and Provis, J. L. (2011a). Mechanical and
thermal characterisation of geopolymers based on silicate-
activated metakaolin/slag blends. Journal of Materials Science,
, 5477–5486. DOI:10.1007/s10853-011-5490-z
https://doi.org/10.1007/s10853-011-5490-z
Bernal, S.A.; Rodríguez, E.D.; Mejia de Gutierrez, R.; Provis,
J.L., and Delvasto, S. (2011b). Activation of Metakaolin/
Slag Blends Using Alkaline Solutions Based on Chemically
Modified Silica Fume and Rice Husk Ash. Waste and Biomass
Valorization, 3, 99–108. DOI:10.1007/s12649-011-9093-3
https://doi.org/10.1007/s12649-011-9093-3
Bernal, S.A; Bejarano, J.; Garzón, C.; Mejía de Gutierrez,
R.; Delvasto, S.; and Rodriguez, E. (2012). Performance
of refractory aluminosilicate particle/fiber-reinforced
geopolymer composites. Composites Part B: Engineering, 43,
-1928
Duxon, P.; Fernández-Jimenéz, A.; Provis, J. L.;
Lukey, G. C.; Palomo, A., and Deventer, J. S. J. (2006).
Geopolymertechnology: the current state of the art. Journal
of Materials Science, 42, 2917–2933. DOI:10.1007/s10853-
-0637-z
Duxon, P.; Lukey, G. C.; Separovic, F.; and Van Deventer,
J. S. J. (2005). Effect of Alkali Cations on Aluminum
Incorporation in Geopolymeric Gels. Industrial and
Engineering Chemistry Research, 44, 832–839. DOI:10.1021/
ie0494216
Fernández-Jimenéz, A.; Pastor, J. Y.; Martín, A.; and Palomo,
A. (2010). High-Temperature Resistance in Alkali-Activated
Cement. Journal of the American Ceramic Society, 93, 3411–
DOI:10.1111/j.1551-2916.2010.03887.x
https://doi.org/10.1111/j.1551-2916.2010.03887.x
HE, P.; Jia, D.; Lin, T.; Wang, M.; and Zhou, Y. (2010). Effects
of high-temperature heat treatment on the mechanical
properties of unidirectional carbon fiber reinforced
geopolymer composites. Ceramics International, 36, 1447–
DOI:10.1016/j.ceramint.2010.02.012
https://doi.org/10.1016/j.ceramint.2010.02.012
Kamseu, E.; Rizzuti, A.; Leonelli, C.; and Perera, D. (2010).
Enhanced thermal stability in K2O-metakaolin-based
geopolymer concretes by Al2O3 and SiO2 fillers addition.
Journal of Materials Science, 45, 1715–1724. DOI:10.1007/
s10853-009-4108-1.
Kong, D. L. Y.; Sanjayan, C. J. G.; and Sagoe-Crentsil, K.
(2008). Factors affecting the performance of metakaolin
geopolymers exposed to elevated temperatures. Journal of
Materials Science, 824–831. DOI:10.1007/s10853-007-2205-6
https://doi.org/10.1007/s10853-007-2205-6
Rodriguez, E. D. (2009). Efecto de las relaciones SiO2/Al2O3
y Na2O/SiO2 en las propiedades de sistemas geopoliméricos
basados en metacaolín. Rev. Fac. Ing. Univ. Antioquia, 49,
-40.
Temuujin, J.; Rickard, W.; Lee, M.; and Van Riessen, A.
(2011). Preparation and thermal properties of fire resistant
metakaolin-based geopolymer-type coatings. Journal of
Non-Crystalline Solids, 357, 1399–1404. DOI:10.1016/j.
jnoncrysol.2010.09.063
Tie-Song, L. I. N.; De-Chang, J. I. A.; Pei-gang, H. E.; and
Mei-rong, W. (2009). Thermal-mechanical properties of
short carbon fiber reinforced geopolymer matrix composites
subjected to thermal load. J. Cent. South Univ. Technol, 16,
−0886 DOI:10.1007/s11771
Xu, H., and Van Deventer, J. S. J. (2000). The geopolymerisation
of alumino-silicate minerals. International Journal of Mineral
Processing, 59, 247–266. DOI:10.1016/S0301-7516(99)00074-5
https://doi.org/10.1016/S0301-7516(99)00074-5
Zivica, V. (2006). Effectiveness of new silica fume alkali
activator. Cement and Concrete Composites,l 28 21–25.
DOI:10.1016/j.cemconcomp.2005.07.004

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Copyright (c) 2019 Servicio Nacional de Aprendizaje (SENA)














